2,905 research outputs found

    Quick connect coupling

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    A coupling device has a transversely arranged, open-end groove in a flange attached to a pipe end. The groove in the flange receives a circumferentially arranged locking flange element on the other coupling member and permits alignment of the bores of the coupling members when the locking flange element is in the open end groove. Upon alignment of the bores of the coupling members, a trigger member is activated to automatically release a spring biased tubular member in one of the coupling members. The tubular member has a conical end which is displaced into the other coupling member to lock the coupling members to one another. A tensioning nut is threadedly movable on a coupling member so as to be moved into tightening engagement with the other coupling member

    The Role of Torsion/Torsion Coupling in the Vibrational Spectrum of Cis−Cis HOONO

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    A three-dimensional model of the vibrational dynamics of HOONO is investigated. This model focuses on the couplings between the OH stretch vibration and the two torsions. The model is based on electronic energies, calculated at the CCSD(T)/cc-pVTZ level of theory and basis and dipole moment functions calculated at the CCSD/aug-cc-pVDZ level. The resulting points were fit to explicit functional forms, and the energies, wave functions, and intensities were evaluated using an approach in which the OH stretching motion was adiabatically separated from the torsional modes. It is found that the HOON torsion is strongly coupled to both the OONO torsion and OH stretch. Despite this, many of the conclusions that were drawn from earlier two-dimensional treatments, which did not include the OONO torsion, hold up on a semiquantitative level. In addition, we use this model to investigate the assignment of recently reported matrix isolated spectra of HOONO and DOONO. Finally, by comparing the results of this three-dimensional calculation to two-dimensional calculations and to the results of second-order perturbation theory, we investigate the question of how one determines the size of the reduced-dimensional system that is needed to describe the vibrational spectrum of molecules, like HOONO, that contain several large amplitude motions

    An address delivered on the occasion of the funeral of the Rev. William James

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    AddressAn Address delivered on the occasion of the funeral of the Rev. William James, D.D. in the First Presbyterian Church, Albany on Wednesday February 19, 1868. By William B. Sprague. Printed by request of the bereaved family

    A Simple Substitute for the Leiter Coil

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    An Address delivered in the Mercer Street Church at the funeral of the Hon. Benjamin Franklin Butler

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    AddressAn address delivered in the Mercer Street Church, New York on December 2, 1858 at the funeral of the Hon. Benjamin Franklin Butler, late attorney general of the United States. By William B. Sprague, D.D. Minister of the Second Presbyterian Congregation in Albany

    Microbial and genetically engineered oils as replacements for fish oil in aquaculture feeds

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    As the global population grows more of our fish and seafood are being farmed. Fish are the main dietary source of the omega-3 (n-3) long-chain polyunsaturated fatty acids (LC-PUFA), eicosapentaenoic (EPA) and docosahexaenoic (DHA) acids, but these cannot be produced in sufficient quantities as are now required for human health. Farmed fish have traditionally been fed a diet consisting of fishmeal and fish oil, rich in n-3 LC-PUFA. However, the increase in global aquaculture production has resulted in these finite and limited marine ingredients being replaced with sustainable alternatives of terrestrial origin that are devoid of n-3 LC-PUFA. Consequently, the nutritional value of the final product has been partially compromised with EPA and DHA levels both falling. Recent calls from the salmon industry for new sources of n-3 LC-PUFA have received significant commercial interest. Thus, this review explores the technologies being applied to producede novon-3 LC-PUFA sources, namely microalgae and genetically engineered oilseed crops, and how they may be used in aquafeeds to ensure that farmed fish remain a healthy component of the human diet

    Encapsulated fish oil products available in the UK meet regulatory guidelines with respect to EPA + DHA contents and oxidative status

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    Encapsulated fish oil products continue to be of high interest, particularly concerning labelling claims and oxidative status. Thus, the present study analysed twenty‐three encapsulated fish oil products from the UK for their lipid and fatty acid composition as well as oxidation parameters. Oil contents ranged from 91.4‐118.9% of the manufacturers stated level. Lipid class analyses revealed three different types of oil products consisting of either triacylglycerol (TAG), ethyl ester (EE) or in combination (EE/TAG). Fatty acid profiles varied according to oil form with long‐chain omega‐3 fatty acids, eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), more concentrated in EE compared to TAG‐based oils with TAG/EE oils containing intermediary levels. Twelve products had EPA + DHA contents lower than advertised, although this was reduced to 11 when the actual measured capsule oil content was taken into consideration. All products had peroxide (PV) and anisidine values below those set by pharmacopeias, although four products had a PV above the industry set limit of 5 meq.kg−1. No relationships were found between oxidative parameters and missing EPA + DHA contents, although a significant relationship was observed between PV and days to expiry. In summary, encapsulated fish oil products on the UK market are not oxidized and meet regulatory guidelines with respect to EPA + DHA contents and oxidative status. Practical Applications: The study highlights the importance of quantifying the actual capsule oil content when determining EPA + DHA levels with respect to label claims. Furthermore, it also places results into context regarding regulatory guidelines demonstrating to regulatory bodies and consumers alike that UK fish oil products do meet specification and are not oxidised

    Flow Through Nanoporous Electrodes in a Microfluidic Fuel Cell

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    ABSTRACT In this paper we present how advection in the electric double layer (EDL) affects the kinetic performance of electrochemical cells. To accomplish this we use a laminar flow fuel cell model based on the Poisson-NernstPlanck and Frumkin-Butler-Volmer equations. The model contains nonlinear physics with very disparate length scales due to the complex 3-dimensional nature of the nano-porous device. To account for these difficulties, the full mathematical model is solved numerically using a novel numerical algorithm developed based on domain decomposition method. Numerical results show that the presence of an advection flux through nano-pores on the order of the EDL width yields some novel physics that affect the structure of electrode-electrolyte interface. We also show that electrolyte advection within the EDL can be used to enhance the kinetic performance of electrodes in electrochemical cells. In the device presented the peak power density can be increased significantly with flow velocity

    Spin susceptibility of the superfluid 3^{3}He-B in aerogel

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    The temperature dependence of paramagnetic susceptibility of the superfluid ^{3}He-B in aerogel is found. Calculations have been performed for an arbitrary phase shift of s-wave scattering in the framework of BCS weak coupling theory and the simplest model of aerogel as an aggregate of homogeneously distributed ordinary impurities. Both limiting cases of the Born and unitary scattering can be easily obtained from the general result. The existence of gapless superfluidity starting at the critical impurity concentration depending on the value of the scattering phase has been demonstrated. While larger than in the bulk liquid the calculated susceptibility of the B-phase in aerogel proves to be conspicuously smaller than that determined experimentally in the high pressure region.Comment: 10 pages, 4 figures, REVTe
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